ArticleThe Journal of organic chemistry2026
Asymmetric Ring Opening of Oxabicyclic Alkenes: Enhanced Rhodium Catalysis Using Camphor-Derived NHC Ligands Featuring Pyridine Coordination.
Article in The Journal of organic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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3 authors.
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Abstract
The synthesis, characterization, and reactivity assessment of a chiral camphor-based Rh(I) catalyst functionalized with a pyridine moiety is presented. The catalytic system was evaluated in the asymmetric ring opening (ARO) of bicyclic alkene substrates, ensuring high product yields and enantioselectivity. While the primary focus was on the use of indoles as nucleophiles in the ARO reaction, a broader scope of bicyclic substrates was also explored. The catalyst demonstrated tolerance toward various functional groups present in the nucleophiles, underscoring its broad synthetic utility in asymmetric synthesis.
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