ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Probing Ultrastrong Through-Space Electronic Coupling in Donor-Acceptor Systems at the Single-Molecule Level.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Through-space donor-acceptor (TSDA) interactions have recently emerged as a new paradigm for charge transfer and transport in organic semiconductors. However, the intrinsic D-A coupling strength and charge transport properties at the molecular level remain unexplored in comparison to established through-bond channels. Here, we employ a variety of single-molecule techniques to directly probe TSDA charge transport characteristics in a series of strategically designed face-to-face D-A systems, revealing that optimized spatial proximity and electronic complementarity yield conductance values up to ∼0.19 G
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