ArticleScientific reports2026
Integrated electrochemical dechlorination and mineralization of diclofenac using CN@PdNi cathode and CN anode for enhanced detoxification.
Article in Scientific reports, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Chlorinated pharmaceuticals like diclofenac (DCF) pose persistent environmental risks due to their bioaccumulation and toxicity, necessitating advanced remediation strategies. Herein, an integrated electrochemical system was developed, combining a self-nitrogen-doped carbon nitride (CN)-supported PdNi (CN@PdNi) cathode for electrocatalytic hydrodechlorination (ECH) with a CN anode for oxidative mineralization in a single, sequential process. The CN@PdNi cathode achieved 98.6% ECH efficiency, selectively cleaving C-Cl bonds to mitigate toxicity, which is attributed to its structural merits, including a well-dispersed, albeit partially clustered, nanoparticle distribution, metallic Pd/Ni phases, predominant Pd
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