Evidence map›Paper›PMID 41484124›Full record

ArticleNature communications2026

Cycloreversion-enhanced toughness and degradability in mechanophore-embedded end-linked polymer networks.

Zhuang Li, Shan Tang

Abstract read
In one paragraph

Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Boosting Natural Rubber Performance by Backbone Rigid Functionalization.Angewandte Chemie (International ed. in English) · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Zhuang LiFrontiers Science Center for Transformative Molecules, Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, China.
Shan TangFrontiers Science Center for Transformative Molecules, Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, China. tang.shan@sjtu.edu.cn.ORCID http://orcid.org/0000-0001-5662-8401

Funding

National Natural Science Foundation of China (National Science Foundation of China) 52473097
6 · The paper itself

Abstract

Enhancing the toughness while achieving triggerable degradation in single-network polymer systems without modifying their inherent chemical composition or network architecture remains a significant challenge. Here we demonstrate a smart end-linked polymer network that "self-strengthen" during use yet "self-destruct" upon certain stimuli. Embedding nonscissile cyclobutane-fused tetrahydrofuran mechanophores within the middle of end-linked polymer networks significantly enhances both toughness and degradability. Under mechanical stress, the force-coupled cycloreversion of these mechanophores releases concealed chain segments, enabling single-network materials to exhibit threefold toughness and tenfold tear energies compared to conventional counterparts. Additionally, ball-milling griding of the bulk material unveils acid-sensitive enol ether units, leading to a markedly improved degradation profile under acidic conditions. This dual effect-originating from the force-coupled cycloreversion of cyclobutane-fused tetrahydrofuran mechanophores-provides an ideal combination of superior mechanical performance and on-demand degradability.

Identifiers

PMID41484124
PMCPMC12895001

What OpenQuestion holds

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LicenceCC BY-NC-ND
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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.