ArticleOrganic letters2026
Mallory-Type Reactivity of 1,2-Dihydroazaborinines: 6π-Electrocyclization-[1,5]-H Shift Cascade toward BN-Doped Polycyclic Frameworks.
Article in Organic letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
1 citing paper in PubMed.
- Substituent Tightrope: Balancing Energy Storage and Stability of Dihydroazaborinine Molecular Solar Thermal Energy Storage Candidates.The Journal of organic chemistry · 2026Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
1,2-Dihydro-1,2-azaborinines exhibit highly selective substitution-dependent photochemistry, yielding either Dewar or benzvalene isomers. Through targeted substitution, an o-BN-terphenyl framework is constructed, which undergoes 6π-electrocyclization upon irradiation. The resulting BN-polyenes rearomatize spontaneously via a [1,5]-hydrogen shift. Under oxidative conditions, an unprecedented BN incorporated triphenylene results. By rationally tuning substitution and reaction conditions, this pathway is favored over Dewar isomer formation, offering selective routes to BN-doped polycyclic frameworks from multiphotoresponsive precursors.
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Registered trials
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