Aluminum Spent Foundry Sand as an Emergent Raw Material in the Production of a Sustainable Aluminosilicate Refractory Castable.

Metal casting industries generate substantial quantities of spent foundry sand (SFS), a silica- and alumina-rich by-product that remains underutilized, with recycling rates below 30%. This study explores the incorporation of aluminum SFS as a secondary raw material in aluminosilicate refractory castables to promote sustainable waste valorization and circular economy practices. Refractory mixtures were prepared with bauxite, kyanite, calcium aluminate cement, microsilica, and flint clay, where fine flint clay was partially replaced by aluminum SFS at 0, 5, 10, and 15 wt.%. Samples were dried at 120 °C and sintered at 850, 1050, and 1400 °C for 4 h. Bulk density, apparent porosity, cold crushing strength, and modulus of rupture were measured, while phase and microstructural evolution were examined by XRD and SEM. The 5 wt.% SFS-containing castable exhibited comparable strength and density to the reference formulation, attributed to the formation of secondary mullite and anorthite that improved matrix cohesion. Higher SFS contents (10-15 wt.%) increased porosity and reduced strength due to excess SiO