ArticleJournal of the American Chemical Society2026
Photochemical Fluoroalkylations with Fluorinated Gases Facilitated by a Robust Metal-Organic Framework.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Electroreductive Radical Olefin Difunctionalization with Fluorinated Gases Enabled by Dosage Delivery from a Metal-Organic Framework.Journal of the American Chemical Society · 2026Article
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Authors and funding
10 authors.
Funding
Abstract
Photochemistry has greatly advanced the sustainable synthesis of complex molecules, but its application for late-stage fluoroalkylation─crucial due to the presence of fluorine in >20% of pharmaceuticals and >65% of agrochemicals─is hindered by the poor atom economy of traditional fluoroalkylating agents. Herein, we demonstrate that simple fluorinated gases, which represent ideal building blocks for fluorochemical synthesis, can be stored within the robust, inexpensive, and redox-innocent metal-organic framework Al-fum to streamline the development of 11 photoinduced fluoroalkylation reactions, including bimolecular homolytic substitution (S
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.