ArticleFundamental research2025
Ligand-modulated regiodivergent alkenylboration of allylarenes: Reaction development and mechanistic study.
Article in Fundamental research, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Who cites it
1 citing paper in PubMed.
- RegiodivergentJACS Au · 2023Review
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5 authors.
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No grant is acknowledged in the PubMed record.
Abstract
Chain-walking has emerged as a promising strategy in organic synthetic methodology, but achieving site-selectivity in reactions involving competition among multiple potential positions remains a challenge. In this study, we presented a novel approach to ligand-modulated, nickel-catalyzed regiodivergent alkenylboration of allylarenes. Our method allows for highly chemoselective preparation of two classes of structurally different alkenyl boronates from the same starting by simply switching the ligand. Mechanistic investigations involving experiments and calculations suggest that the ligand-modulating regiodivergence arises from either regioselective
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