ArticleThe journal of physical chemistry. B2026
Do Dipolar Cosolvents Mitigate Microheterogeneity in Deep Eutectic Solvents? Solvation Dynamics and Solute Rotations in Glyceline/Methanol Solutions.
Article in The journal of physical chemistry. B, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Steady-state and time-resolved fluorescence was used to investigate the solvation and rotational dynamics of coumarin 153 (C153) and coumarin 343 (C343) in binary solutions of methanol and glyceline, a deep eutectic solvent (DES) composed of a 1:2 molar ratio of choline chloride and glycerol. Time-resolved Stokes shifts were used to quantify the solvation dynamics and were found to be biexponential for both C153 and C343 with nearly identical integral solvation times. The solvation times were also found to be weakly dependent upon solution viscosity, and a power law exponent of
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