ArticleThe Journal of organic chemistry2026
Enantioconvergent Synthesis of Diarylmethane Drugs via Privileged Benzhydrol Intermediates.
Article in The Journal of organic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The benzhydryl motif is a privileged pharmacophore in antihistaminic and neuroactive drugs. We present a broadly applicable, enantioconvergent synthesis of benzhydrols via asymmetric migratory Tsuji-Wacker oxidation of stilbenes. This constitutionally stereodivergent protocol operates without preactivated or sterically biased substrates, affording chiral α,α-diaryl ketones in up to 91%
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