Evidence map›Paper›PMID 41446541›Full record

ArticleACS catalysis2025

Mechanistically Driven Development of Kumada Catalyst-Transfer Polymerizations: A Rapid Injection NMR Study.

Seokmin Kang, Wentao Cen, Achyut Ranjan Gogoi, Jeanette Piña, Adhya Suresh, Fernando Ramirez, Osvaldo Gutierrez, Andy A Thomas

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ACS catalysis, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Seokmin KangDepartment of Chemistry, Texas A&M University, College Station, Texas 77845, United States.
Wentao CenDepartment of Chemistry, Texas A&M University, College Station, Texas 77845, United States.
Achyut Ranjan GogoiDepartment of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, California 90095, United States.ORCID https://orcid.org/0000-0002-7609-3720
Jeanette PiñaDepartment of Chemistry, Texas A&M University, College Station, Texas 77845, United States.
Adhya SureshDepartment of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, California 90095, United States.
Fernando RamirezDepartment of Chemistry, Texas A&M University, College Station, Texas 77845, United States.
Osvaldo GutierrezDepartment of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, California 90095, United States.ORCID https://orcid.org/0000-0001-8151-7519
Andy A ThomasDepartment of Chemistry, Texas A&M University, College Station, Texas 77845, United States.ORCID https://orcid.org/0000-0001-6336-5566

Funding

New Directions in Sustainable Open-Shell Radical C-C Bond Formations Enabled by Merging Modern Computational and Experimental MethodsR35GM137797 · NIGMS · UNIV OF MARYLAND, COLLEGE PARK · PI Osvaldo Gutierrez · 2020 to 2026
$2.7M
NIGMS NIH HHS R35 GM137797
6 · The paper itself

Abstract

Transmetalation is a pivotal step in the Kumada-Tamao-Corriu cross-coupling reaction, yet its mechanistic details have remained relatively unexplored compared to other palladium-catalyzed processes. Herein, we systematically investigate how diverse phosphine ligands influence the transmetalation rate, using rapid injection NMR (RI-NMR) to directly monitor the formation of the cross-coupling product. The study reveals that both ligand electronic and steric effects significantly affect

Indexed as

Biarylmonophosphine LigandCatalyst Transfer PolymerizationKumada−Tamao−Corriu Cross CouplingPalladium Catalyzed Cross CouplingRapid Injection NMR SpectroscopyTransmetalation

Identifiers

PMID41446541
PMCPMC12723679

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.