ArticleJournal of the American Chemical Society2026
A Note on Why Low-Symmetry Lanthanide Clusters Can Be Good Single Molecule Magnets.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Lanthanide complexes with a low-symmetry ligand environment are frequently observed to exhibit good single molecule magnet (SMM) behavior, which is seemingly at odds with the established understanding that strong Ising-type magnetic anisotropy is essential. This and other paradoxical features of such clusters are shown to follow naturally from a semiclassical treatment of the ligand field, which becomes valid in the limit of large total angular momentum
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