A Paradigm Shift in End-of-Life Membrane Recycling: From Conventional to Emerging Techniques.

The conventional linear life cycle of membrane materials, spanning fabrication, use, and disposal through landfilling or incineration poses serious sustainability challenges. The environmental burden associated with both the production of new membranes and the disposal of end-of-life (EoL) modules is considerable, further intensified by the reliance on fossil fuel-derived polymers, toxic solvents, and resource-intensive manufacturing processes. These challenges underscore the urgent need to integrate sustainability principles across the entire membrane life cycle, from raw material selection to reuse and regeneration. Emerging approaches such as membrane regeneration using recyclable polymers based on covalent adaptable networks (CANs) have introduced a new paradigm of closed-loop design, enabling complete depolymerization and reformation. In parallel, more conventional strategies, including the valorization of recycled plastic waste and the upcycling or downcycling of EoL membranes, offer practical routes toward a circular membrane economy. In this review, we consolidate current advances in membrane recycling, critically evaluate their practical constraints, and delineate the technical and environmental challenges that must be addressed for broader implementation. The insights presented here aim to guide the development of next-generation circular membrane technologies that harmonize sustainability with performance.