ReviewNational science review2025
Decoding heterogeneous electrocatalysts for acidic oxygen evolution: mechanisms, rational design and AI acceleration.
Review in National science review, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Authors and funding
11 authors.
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Abstract
Proton exchange membrane water electrolyzers (PEMWEs) are positioned as a transformative technology for renewable energy conversion and storage systems. The acidic oxygen evolution reaction (AOER), serving as the pivotal half-reaction governing overall efficiency, operational stability and system cost in water electrolysis, has become a focal point of contemporary electrochemical research. In this Review, we comprehensively summarize the recent advancements in both noble metal-based (Ir and Ru) and non-noble-metal-based (Mn and Co) heterogeneous electrocatalysts (HEs) for the AOER. The analysis commences with fundamental AOER mechanisms and the key factors that influence them, elucidating critical structure-activity relationships essential for rational catalyst engineering. Subsequently, we systematically evaluate state-of-the-art design strategies and corresponding breakthroughs in catalyst development, followed by a forward-looking perspective on the emergence and application of AI for science in the AOER. This review provides valuable guidance for the design of next-generation HEs for the AOER, ultimately aiming to bridge the gap between laboratory-scale achievements and industrial implementation of PEMWE technologies.
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