Evidence map›Paper›PMID 41431347›Full record

ArticleAdvanced materials (Deerfield Beach, Fla.)2026

Structural Exploration of Zirconium Metal-Organic Frameworks Through Linker Desymmetrization and Modulator Compensation.

Rong-Ran Liang, Kun-Yu Wang, Zongsu Han, Kui Tan, Yihao Yang, Zhaoyi Liu, Joshua Rushlow, Jiatong Huo, Hong-Cai Zhou

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Rong-Ran LiangDepartment of Chemistry, Texas A&M University, College Station, Texas, USA.
Kun-Yu WangDepartment of Chemistry, Texas A&M University, College Station, Texas, USA.
Zongsu HanDepartment of Chemistry, Texas A&M University, College Station, Texas, USA.
Kui TanDepartment of Chemistry, University of North Texas, Denton, Texas, USA.
Yihao YangDepartment of Chemistry, Texas A&M University, College Station, Texas, USA.
Zhaoyi LiuDepartment of Chemistry, Texas A&M University, College Station, Texas, USA.
Joshua RushlowDepartment of Chemistry, Texas A&M University, College Station, Texas, USA.
Jiatong HuoDepartment of Chemistry, Texas A&M University, College Station, Texas, USA.
Hong-Cai ZhouDepartment of Chemistry, Texas A&M University, College Station, Texas, USA.ORCID https://orcid.org/0000-0002-9029-3788

Funding

Robert A. Welch Foundation through a Welch Endowed Chair to H.-C.Z. A-0030U.S. Department of Energy, Office of Fossil Energy DE-FE0032108U.S. Department of Energy, Office of Fossil Energy/Pennsylvania State University S000655-DOE
6 · The paper itself

Abstract

Zirconium-based metal-organic frameworks (Zr-MOFs) feature exceptional thermal/chemical stability among various MOFs, enabling diverse applications. Their material properties are highly dependent on molecular structures consisting of Zr-clusters and organic linkers. However, structural diversity in Zr-MOFs remains constrained by the limited variety of known Zr-clusters and the predominance of high-symmetry linkers, which stems from the inherent symmetry constraints presented by Zr-clusters. In this work, we develop a linker-desymmetrization-modulator-compensation (LDMC) strategy to construct Zr-MOFs with enhanced structural diversity. This approach reduces linker symmetry to create structural defects in Zr-clusters, while such a thermodynamically unfavorable process can be compensated for by the coordination of modulators, such as benzoic acid and formic acid. As a result, two MOFs, PCN-1005 and PCN-1006, with unprecedented Zr-clusters have been constructed. PCN-1005 features an asymmetric Zr

Indexed as

linker‐desymmetrization‐modulator‐compensationmetal–organic frameworksordered structural defectsselective gas adsorption

Identifiers

PMID41431347
PMCPMC12910544

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.