Synthesis, structural characterization, and reactivity of homocatenated Ga₄ complexes with unsaturated Ga-Ga=Ga-Ga chains.

Ning Zhang, Bing Wang, Yanliang Wu, Wenhao Chen, Shuxia Zhu, Linfang Lu, Zhigang Ni, Di Wu

Abstract read

In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

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2 · The registry

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3 · Its place in the literature

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0 citing papers in PubMed.

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4 · The record

Corrections and comments

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5 · Who and what money

Authors and funding

8 authors.

Ning Zhang *Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Zhejiang Key Laboratory of Organosilicon Material Technology, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, Zhejiang, China.

Bing Wang *Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Zhejiang Key Laboratory of Organosilicon Material Technology, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, Zhejiang, China.

Yanliang WuKey Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Zhejiang Key Laboratory of Organosilicon Material Technology, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, Zhejiang, China.

Wenhao ChenKey Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Zhejiang Key Laboratory of Organosilicon Material Technology, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, Zhejiang, China.

Shuxia ZhuKey Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Zhejiang Key Laboratory of Organosilicon Material Technology, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, Zhejiang, China.

Linfang LuKey Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Zhejiang Key Laboratory of Organosilicon Material Technology, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, Zhejiang, China.ORCID http://orcid.org/0000-0002-8747-4174

Zhigang NiKey Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Zhejiang Key Laboratory of Organosilicon Material Technology, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, Zhejiang, China.ORCID http://orcid.org/0000-0002-0109-3275

Di WuKey Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Zhejiang Key Laboratory of Organosilicon Material Technology, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, Zhejiang, China. wudi@hznu.edu.cn.ORCID http://orcid.org/0000-0002-7350-140X

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22001053Natural Science Foundation of Zhejiang Province (Zhejiang Provincial Natural Science Foundation) LQ20B010007

6 · The paper itself

Abstract

The homocatenation of electron-deficient Group 13 metals to form metal-metal multiple bonds through covalent self-assembly remains extremely challenging. Herein we demonstrate the synthesis and characterizations of N-heterocyclic carbene (NHC)-stabilized digallyl digallenes (1a and 1b), which exhibit unsaturated Ga-Ga=Ga-Ga chains with trans-bent geometries. These compounds were synthesized through salt-metathesis reactions using Cp*Ga, (L

Identifiers

PMID41429787

DOI10.1038/s41467-025-67892-1

PMCPMC12749812

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.