Catalyst-Controlled, Regiodivergent Aminooxygenation Reactions of Dienes.

Caitlyn P McNichol, Liván Borrego, Erhan Ertekin, Shauna M Paradine

Abstract read

In one paragraph

Article in The Journal of organic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

Catalyst-Controlled, Regiodivergent Aminooxygenation Reactions of Dienes.The Journal of organic chemistry · 2026
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Caitlyn P McNicholDepartment of Chemistry, University of Rochester, 120 Trustee Rd, Rochester, New York 14627, United States.ORCID 0000-0002-3592-628X

Liván BorregoDepartment of Chemistry, University of Rochester, 120 Trustee Rd, Rochester, New York 14627, United States.ORCID 0000-0003-2389-9429

Erhan ErtekinDepartment of Chemistry, University of Rochester, 120 Trustee Rd, Rochester, New York 14627, United States.

Shauna M ParadineDepartment of Chemistry, University of Rochester, 120 Trustee Rd, Rochester, New York 14627, United States.ORCID 0000-0002-6181-7431

Funding

Discovering catalytic strategies for transition metal-catalyzed reactions to construct topologically complex organic scaffoldsR35GM150584 · NIGMS · UNIVERSITY OF ROCHESTER · PI Shauna M Paradine · 2023 to 2026

$1.3M

NIGMS NIH HHS R35 GM150584

6 · The paper itself

Abstract

We report a method for an aerobic, regiodivergent aminooxygenation of dienes via catalyst control. A simple switch in the copper catalyst source allows for selective access to either the 1,2- or 1,4-aminooxygenated product from a single starting material. Mechanistic studies indicate that the coordinating ligand on the copper salt is responsible for the divergent regiochemical outcomes and that the origin of regiodivergence lies in competing mechanisms for oxygen delivery to the carbon-centered radical intermediate.

Identifiers

PMID41427942

DOI10.1021/acs.joc.5c02010

PMCPMC12797283

What OpenQuestion holds

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LicenceCC BY

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.