ArticleACS engineering Au2025
Optimizing Mixtures of Metal-Organic Frameworks for Robust and Bespoke Passive Atmospheric Water Harvesting.
Article in ACS engineering Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Atmospheric water harvesting (AWH) is a method to obtain clean water in remote or underdeveloped regions including, but not limited to, those with an arid or desert climate. For passive (i.e., relying on ambient cooling and, for heating, natural sunlightas opposed to an external power source), adsorbent-based AWH, an adsorbent bed is employed to capture water from cold, humid air at nighttime, while during the daytime the bed is then exposed to natural sunlight to heat it and desorb the water for collection. Metal-organic frameworks (MOFs) are tunable, nanoporous materials with suitable water adsorption properties for comprising this adsorbent bed. The water delivery by the MOF adsorbent bed in a passive AWH device depends on (1) the nighttime, capture conditions (temperature and humidity) and daytime, release conditions (temperature, humidity, and solar flux) and (2) the structure(s) of the MOF(s) comprising the bed, which dictate MOF-water interactions. Notably, the capture and release conditions vary from region-to-region and season-to-season and fluctuate from day-to-day, while different MOFs offer different water adsorption isotherms. Consequently, we propose (1) comprising the adsorbent bed for passive AWH with a
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