Evidence map›Paper›PMID 41423927›Full record

ArticleJournal of the American Chemical Society2026

Isolation of a Terminal Cobalt Nitride in a Metal-Organic Framework.

Jonas Börgel, Nicole Removski, Jordan W Taylor, Zikri Hasanbasri, Khetpakorn Chakarawet, Alexander J Heyer, Patrick W Smith, N Isaac Zakaria, Danh X Ngo, Ryan A Klein and 19 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

29 authors.

Jonas BörgelDepartment of Chemistry, University of California, Berkeley, California 94720, United States.ORCID 0000-0001-5301-8579
Nicole RemovskiDepartment of Chemistry, University of California, Berkeley, California 94720, United States.ORCID 0000-0003-1437-5762
Jordan W TaylorDepartment of Chemistry, University of California, Berkeley, California 94720, United States.
Zikri HasanbasriDepartment of Chemistry, University of California, Davis, California 95616, United States.
Khetpakorn ChakarawetDepartment of Chemistry, University of California, Davis, California 95616, United States.
Alexander J HeyerDepartment of Chemistry, University of California, Berkeley, California 94720, United States.ORCID 0000-0003-4362-8191
Patrick W SmithChemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.ORCID 0000-0001-5575-4895
N Isaac ZakariaMaterials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.ORCID 0000-0001-8990-1785
Danh X NgoDepartment of Chemistry, University of California, Berkeley, California 94720, United States.
Ryan A KleinDepartment of Chemistry, University of California, Berkeley, California 94720, United States.
Maria V PaleyDepartment of Chemistry, University of California, Berkeley, California 94720, United States.
Vincent R AllenDepartment of Chemistry, University of California, Berkeley, California 94720, United States.
Chaochao DunThe Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.ORCID 0000-0002-3215-6478
Henry Z H JiangDepartment of Chemistry, University of California, Berkeley, California 94720, United States.
Nykita Z RustadDepartment of Chemistry, University of California, Berkeley, California 94720, United States.ORCID 0009-0009-4788-3860
Tieyan ChangAdvanced Photon Source, Argonne National Laboratory, Lemont, Illinois 60439, United States.ORCID 0000-0002-7434-3714
Ying-Pin ChenAdvanced Photon Source, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Mauricio Lopez LunaChemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.
Wanli YangAdvanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.ORCID 0000-0003-0666-8063
Brandon R BarnettDepartment of Chemistry, University of California, Berkeley, California 94720, United States.ORCID 0000-0002-3113-7347
Jeffrey A ReimerDepartment of Chemical and Biomolecular Engineering, University of California, Berkeley, California 94720, United States.
Yu-Sheng ChenAdvanced Photon Source, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Jeffrey J UrbanMaterials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.ORCID 0000-0003-4909-2869
Monika BlumChemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.ORCID 0000-0002-2918-9092
Stefan G MinasianChemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.ORCID 0000-0003-1346-7497
Edward I SolomonDepartment of Chemistry, Stanford University, Stanford, California 94305, United States.
R David BrittDepartment of Chemistry, University of California, Davis, California 95616, United States.ORCID 0000-0003-0889-8436
T David HarrisDepartment of Chemistry, University of California, Berkeley, California 94720, United States.ORCID 0000-0003-4144-900X
Jeffrey R LongDepartment of Chemistry, University of California, Berkeley, California 94720, United States.ORCID 0000-0002-5324-1321

Funding

Structure/Function Correlations Over Copper EnzymesR01DK031450 · NIDDK · STANFORD UNIVERSITY · PI EDWARD I SOLOMON · 1986 to 2026
$8.7M
NIDDK NIH HHS R01 DK031450
6 · The paper itself

Abstract

Transition metal nitrides are reactive intermediates in biological and industrial processes. Chemists have synthesized molecular model complexes of such reactive species to understand their function and electronic requirements for new applications. However, molecular chemistry can suffer from intra- and intermolecular decomposition pathways, which preclude further discovery of unknown reactive species. Metal-organic frameworks offer an opportunity for creating long-lived forms of such species with the vacuum of the pore suppressing degradation while simultaneously enabling substrate access for controlled reactivity studies. Here, we report the characterization of an elusive terminal cobalt nitride species generated through photolysis or thermolysis of a site-isolated cobalt azide within the evacuated metal-organic framework CoN

Identifiers

PMID41423927
PMCPMC13154729

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.