ArticleThe journal of physical chemistry. B2026
Nonlocal Response in Electrolytic Cells: A Generalized Poisson-Nernst-Planck Model with Memory Effects.
Article in The journal of physical chemistry. B, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
We present an extension of the standard Poisson-Nernst-Planck model by incorporating temporal memory effects to describe the spectroscopy impedance response in electrolytic systems. This model yields a modified current-density relation in which the ionic flux depends nonlocally on the applied electric field. The resulting electrical impedance may exhibit non-Debye relaxation and fractional-like scaling at low frequencies, providing a basis for anomalous diffusion in confined electrolytes. We analyze impedance spectroscopy data from NH
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