Evidence map›Paper›PMID 41417913›Full record

ArticleScience advances2025

Photoredox-controlled chemo-divergent, regio-, and stereoselective difunctionalization of olefins via switchable SO

Jiuli Xia, Lihan Zhu, Zhiguang Lv, Yunliang Guo, Lefeng Lin, Jiaqiong Sun, Guangfan Zheng, Qian Zhang

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Article in Science advances, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Jiuli XiaDepartment of Chemistry, Northeast Normal University, Changchun 130024, China.ORCID 0009-0004-0022-0991
Lihan ZhuDepartment of Chemistry, Northeast Normal University, Changchun 130024, China.ORCID 0000-0002-1213-5717
Zhiguang LvDepartment of Chemistry, Northeast Normal University, Changchun 130024, China.ORCID 0009-0002-4307-8943
Yunliang GuoDepartment of Chemistry, Northeast Normal University, Changchun 130024, China.ORCID 0009-0003-0060-9860
Lefeng LinDepartment of Chemistry, Northeast Normal University, Changchun 130024, China.ORCID 0009-0006-0260-9436
Jiaqiong SunDepartment of Chemistry, Northeast Normal University, Changchun 130024, China.ORCID 0000-0002-8724-2664
Guangfan ZhengDepartment of Chemistry, Northeast Normal University, Changchun 130024, China.ORCID 0000-0003-0201-6279
Qian ZhangDepartment of Chemistry, Northeast Normal University, Changchun 130024, China.ORCID 0000-0002-3136-841X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

While radical difunctionalization offers substantial potential for molecular diversification, existing methodologies predominantly focus on styrenes and activated alkenes, leaving fundamental light olefins (e.g., ethylene and propylene) largely unexplored. Moreover, achieving stereoselective transformations of light olefins remains a formidable challenge. Here, we present a visible-light-mediated photoredox-catalyzed chemo-divergent and regioselective radical difluoromethylation/polyfluoroarylsulfonylation and difluoromethylation/polyfluoroarylation of structurally diverse alkenes through switchable sulfur dioxide reintegration. The method demonstrates broad applicability across styrenes, unactivated alkenes, and gaseous ethylene/propylene substrates. The photocatalyst functions as a switch, and Sodium difluoromethanesulfinate (CF

Identifiers

PMID41417913
PMCPMC12716424

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