Evidence map›Paper›PMID 41413328›Full record

ArticleCommunications chemistry2025

Ring expansion of osmacyclopentadiene affords diverse six-membered osmaaromatics.

Yue Zhao, Bingjie Fu, Yang Li, Di Liu, Wei Bai

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Communications chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Yue ZhaoSchool of Chemistry, Dalian University of Technology, Dalian, 116024, P. R. China.
Bingjie FuSchool of Chemistry, Dalian University of Technology, Dalian, 116024, P. R. China.
Yang LiSchool of Chemical Engineering, Ocean and Life Sciences, Dalian University of Technology, Panjin, 124221, P. R. China. chyangli@dlut.edu.cn.ORCID http://orcid.org/0000-0002-5719-9044
Di LiuSchool of Chemistry, Dalian University of Technology, Dalian, 116024, P. R. China. liudi@dlut.edu.cn.ORCID http://orcid.org/0000-0003-3602-770X
Wei BaiSchool of Chemistry, Dalian University of Technology, Dalian, 116024, P. R. China. baiwei@dlut.edu.cn.ORCID http://orcid.org/0000-0001-8585-9321

Funding

Natural Science Foundation of Liaoning Province (Liaoning Provincial Natural Science Foundation) 2025-MS-001
6 · The paper itself

Abstract

Metallaromatics such as metallabenzene and its heteroatom-containing analogues have aroused interests both in experimental and theoretical studies. While various six-membered metallaaromatics have been explored, a general synthetic methodology is still undeveloped. Herein, we report the skeletal editing of five-membered metallacyclopentadiene involving the insertion of the sixth atoms (S, Se, N, C) into the Os-C bond, as a general approach for osmafluoranthene derivatives containing osmathiabenzene, osmaselenabenzene, osmapyridine, and osmabenzene units. These complexes show broad UV-Vis absorptions, and their aromaticity has been authenticated spectroscopically, structurally and computationally.

Identifiers

PMID41413328
PMCPMC12714836

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.