ArticleNature communications2025
Isolation and reactivity of sodium benzyl cations.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
2 citing papers in PubMed.
- Alkali-metal alkoxides as additives in polar organometallic chemistry for M-H and M-X exchange reactions.Chemical Society reviews · 2026Review
- Comparisons and Contrasts in a Complete Set of Alkali Metal Cumyl Structures.Inorganic chemistry · 2026Article
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Authors and funding
6 authors.
Funding
Abstract
Carbanions are an important class of reactive species used as nucleophiles in C-C bond-forming reactions. Such reactive carbanions are generated by deprotonating relatively acidic C-H bonds using strong bases like sodium/potassium hydroxides or amides. Lochmann-Schlosser base, consisting of a mixture of alkyl lithium reagents and heavier alkali metal alkoxides, is widely used for the metalation of organic compounds via the deprotonation of weakly acidic C-H bond. The aggregation of alkoxides makes it challenging to understand the course of the reaction, demanding the consideration of molecular compounds as alternatives to sodium/potassium alkoxides. Here, we demonstrate the development of new organosodium reagents using molecular compounds as alternatives to oligomeric sodium/potassium alkoxides. Sodium tris(3,5-dimethylpyrazolyl)borate, along with mesityllithium in the presence of tris[2-(dimethylamino)ethyl]amine (Me
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Registered trials
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