ArticleNature communications2025
Hg-free electro-thermal cascade catalysis for acetylene upgrading into polyvinyl chloride precursor.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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15 authors.
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Abstract
Acetylene hydrochlorination is the predominant route for producing polyvinyl chloride (PVC) precursors in coal-rich, oil-poor regions. However, this conventional thermocatalytic pathway inevitably uses Hg-based catalysts, which pose serious threats to the environment and human health. Here, we propose an alternative cascade conversion strategy that efficiently converts acetylene to pure dichloroethane (PVC precursor) under ambient conditions without using Hg-based catalysts. This strategy couples an electrocatalytic reactor with a thermocatalytic reactor. In the electrocatalytic reactor, highly selective formation of C₂H₄ (FE
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