Terrestrial atmospheric ion implantation occurred in the nearside lunar regolith during the history of Earth's dynamo.

Light volatile elements in the lunar regolith are thought to be a mixture of the solar wind and Earth's atmosphere, the latter sourced in the absence of geomagnetic field. However, the extent to which both the current and primitive geodynamo influence the transport of terrestrial ions still remains unclear, and this uncertainty is further complicated by the enigmatic composition and poorly constrained location of the Eoarchean exosphere. Here we use three-dimensional magnetohydrodynamic numerical simulations with contemporary magnetized and Archean unmagnetized atmospheres to investigate how Earth's intrinsic magnetic field affects this transfer, aiming to constrain how and when the lunar isotopic signature provides a record of Earth's paleoatmosphere. We find that atmospheric transfer is efficient only when the Moon is within Earth's magnetotail. The non-solar contribution to the lunar soil is best explained by implantation during the long history of the geodynamo under present-day solar wind conditions, rather than by any brief, putatively unmagnetized epoch of the early Archean Earth. This further suggests the history of the terrestrial atmosphere, spanning billions of years, could be preserved in buried lunar soils. Our results indicate that the elemental abundances of Apollo samples are highly sensitive to Earth's hydrodynamic escape boundary, which, at the time of ion implantation, was never smaller than 190 km.