Evidence map›Paper›PMID 41389009›Full record

ArticleACS applied materials & interfaces2025

Mechanistic Insights in Acceptorless Dehydrogenation of N-Heterocycles Using Graphenes as Carbocatalysts.

Andrés Mollar-Cuni, Pablo García-Aznar, Santiago Martín, German Sastre, Hermenegildo García, Jose A Mata

Abstract read
In one paragraph

Article in ACS applied materials & interfaces, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0cells of the map it votes in
0citing papers in PubMed
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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Andrés Mollar-CuniInstitute of Advanced Materials (INAM), Universitat Jaume I, Avda. Sos Baynat s/n, 12006 Castellón, Spain.
Pablo García-AznarInstituto de Tecnología Química, Consejo Superior de Investigaciones Científicas─Universitat Politècnica de València, Avda. Los Naranjos s/n, 46022 Valencia, Spain.
Santiago MartínInstituto de Nanociencia y Materiales de Aragón (INMA), CSIC─Universidad de Zaragoza, 50009, Zaragoza, Spain.
German SastreInstituto de Tecnología Química, Consejo Superior de Investigaciones Científicas─Universitat Politècnica de València, Avda. Los Naranjos s/n, 46022 Valencia, Spain.ORCID 0000-0003-0496-6331
Hermenegildo GarcíaInstituto de Tecnología Química, Consejo Superior de Investigaciones Científicas─Universitat Politècnica de València, Avda. Los Naranjos s/n, 46022 Valencia, Spain.ORCID 0000-0002-9664-493X
Jose A MataInstitute of Advanced Materials (INAM), Universitat Jaume I, Avda. Sos Baynat s/n, 12006 Castellón, Spain.ORCID 0000-0001-9310-2783

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Catalytic dehydrogenation is a critical transformation in the chemical and energy sectors, particularly for reversible hydrogen storage systems. One of the most promising systems for hydrogen storage is the development of liquid organic hydrogen carriers (LOHCs), which have the potential capacity of storing and releasing hydrogen gas on demand. Catalytic direct dehydrogenation represents a greener, promising method to generate hydrogen in situ from these hydrogen-dense carriers. The catalytic activity of graphene materials as metal-free carbocatalysts in the acceptorless dehydrogenation of N-heterocycles has been explored. Herein, a detailed mechanistic investigation has been conducted through both experimental (stoichiometric and masking experiments) and DFT calculations on the reaction mechanism. The proposed mechanism identifies

Indexed as

acceptorless dehydrogenationcarbocatalysisgrapheneN-heterocyclesreaction mechanism

Identifiers

PMID41389009
PMCPMC12754750

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.