Evidence map›Paper›PMID 41388330›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2026

Oxidative Addition of C-F Bonds to the Phosphoranide Ion [P(C

Lukas Hartmann, Beate Neumann, Hans-Georg Stammler, Mira Kessler, Berthold Hoge

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Oxidative Addition of C-F Bonds to the Phosphoranide Ion [P(CChemistry (Weinheim an der Bergstrasse, Germany) · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Lukas HartmannFakultät für Chemie, Centrum für Molekulare Materialien, Universität Bielefeld, Bielefeld, Germany.
Beate NeumannFakultät für Chemie, Centrum für Molekulare Materialien, Universität Bielefeld, Bielefeld, Germany.
Hans-Georg StammlerFakultät für Chemie, Centrum für Molekulare Materialien, Universität Bielefeld, Bielefeld, Germany.
Mira KesslerDepartment of Chemistry, Henry Bellmon Research Center, Oklahoma State University, Stilwater, USA.ORCID https://orcid.org/0000-0002-2242-239X
Berthold HogeFakultät für Chemie, Centrum für Molekulare Materialien, Universität Bielefeld, Bielefeld, Germany.ORCID https://orcid.org/0000-0001-9610-8478

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Oxidative additions of C─Hal bonds (Hal  =  F, Cl, Br, I) are widely known for a variety of transition metal complexes owing to their range of oxidation states and flexible coordination sphere. Low valent main group element compounds were shown to mimic this reaction behavior, due to the propensity of changing their oxidation state and coordination number by +2. Yet the addition to C─F bonds is especially challenging due to a large bond dissociation energy. While several examples are known for compounds from group 13 and 14, only few reports demonstrate this type of reaction for compounds from group 15. Herein we report the first anionic P(III) species undergoing an oxidative addition of C─F bonds. The tetracoordinated [P(C

Indexed as

C─F bond activationphosphatephosphoranide

Identifiers

PMID41388330
PMCPMC12790317

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.