Exploring the Boundaries of Cyclometalated Iridium(III) Sensitizers in Photoelectrochemical Organic Transformations.

Andrea Mantovani, Annagioia Mastrolorenzo, Edoardo Marchini, Paola Manini, Mirco Natali

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In one paragraph

Article in ACS applied materials & interfaces, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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2 · The registry

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4 · The record

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5 · Who and what money

Authors and funding

5 authors.

Andrea MantovaniDepartment of Chemical, Pharmaceutical and Agricultural Sciences (DOCPAS), University of Ferrara, Via L. Borsari 46, Ferrara 44121, Italy.

Annagioia MastrolorenzoDepartment of Chemical Sciences, University of Naples Federico II, Via Cintia 4, Naples 80126, Italy.

Edoardo MarchiniDepartment of Chemical, Pharmaceutical and Agricultural Sciences (DOCPAS), University of Ferrara, Via L. Borsari 46, Ferrara 44121, Italy.

Paola ManiniDepartment of Chemical Sciences, University of Naples Federico II, Via Cintia 4, Naples 80126, Italy.ORCID 0000-0003-2842-5011

Mirco NataliDepartment of Chemical, Pharmaceutical and Agricultural Sciences (DOCPAS), University of Ferrara, Via L. Borsari 46, Ferrara 44121, Italy.ORCID 0000-0002-6638-978X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Dye-sensitized photoelectrochemical cells (DSPECs) are currently at the forefront of solar-to-chemical energy conversion technologies. Although water oxidation to dioxygen has long been the preferred reaction at the photoanodic compartment, recent research has increasingly focused on oxidation processes for the synthesis of value-added organic compounds. Quite surprisingly, within this framework, cyclometalated iridium(III) complexes have received negligible attention as photoactive components in DSPEC photoanodes, in spite of their intriguing photophysical and electrochemical properties. With the aim of filling this gap, this work explores the application of two iridium(III) complexes (

Indexed as

benzyl alcoholDSPECiridium(III) complexesoxidationphotoelectrochemistryradical cation Diels−Aldervalue-added organics

Identifiers

PMID41385251

DOI10.1021/acsami.5c20212

PMCPMC12754757

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