ArticleUltrasonics sonochemistry2026
Ultrasonic cavitation-induced radical processes for tetracycline degradation and Cr(VI) reduction: Highlighting the pivotal role of Cr(V) intermediates.
Article in Ultrasonics sonochemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Tetracycline (TC) and Cr(VI) often co-occur in wastewaters, where their synergistic toxicity and contrasting redox behaviors complicate remediation. In this study, ultrasonic cavitation was employed as a employed as a green and efficient process to simultaneously degrade TC and reduce Cr(VI). Under optimal conditions (20 kHz, 12 mm probe, 131 μm amplitude, 308 K), TC and Cr(VI) removal reached 62.9 % and 70.8 % within 2 h, respectively. The synergistic mechanism was elucidated through radical quenching, electron paramagnetic resonance (EPR) spectroscopy, and complementary computational fluid dynamics (CFD) simulations and density functional theory (DFT) calculations. Cavitation bubble collapse generated both oxidative and reductive radicals, enabling concurrent oxidation and reduction. Radical identification showed that ·O
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