Evidence map›Paper›PMID 41369190›Full record

ArticleAngewandte Chemie (International ed. in English)2026

Tracking Structural and Electron Spin Density Changes in a Cooperative Mn

Wassilios Papawassiliou, José P Carvalho, Subhradip Paul, Aizuddin Sultan, Michael Fardis, Georgios Papavassiliou, Grace G Morgan, Katharina Märker, Gaël De Paëpe

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Tracking Structural and Electron Spin Density Changes in a Cooperative MnAngewandte Chemie (International ed. in English) · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Wassilios PapawassiliouUniv, Grenoble Alpes, CEA, IRIG, MEM, Grenoble, 38000, France.
José P CarvalhoInterdisciplinary Nanoscience Center (iNANO) and Department of Chemistry, Aarhus University, Gustav Wieds Vej 14, Aarhus C, DK-8000, Denmark.
Subhradip PaulUniv, Grenoble Alpes, CEA, IRIG, MEM, Grenoble, 38000, France.
Aizuddin SultanSchool of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland.
Michael FardisInstitute of Nanoscience and Nanotechnology, NCSR "DEMOKRITOS", 153 41 Ag. Paraskevi - Attiki, Athens, Greece.
Georgios PapavassiliouInstitute of Nanoscience and Nanotechnology, NCSR "DEMOKRITOS", 153 41 Ag. Paraskevi - Attiki, Athens, Greece.
Grace G MorganSchool of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland.
Katharina MärkerUniv, Grenoble Alpes, CEA, IRIG, MEM, Grenoble, 38000, France.
Gaël De PaëpeUniv, Grenoble Alpes, CEA, IRIG, MEM, Grenoble, 38000, France.ORCID https://orcid.org/0000-0001-9701-3593

Funding

French National Research Agency ANR17-EURE-0003French National Research Agency ANR-19-CE29-0021Frontiers for the Future Award 19/FFP/6909IR INFRANALYTICS FR2054LabEx Arcane ANR-15-IDEX-02Science Foundation Ireland (SFI) with a US-Ireland Award 19/US/3631
6 · The paper itself

Abstract

Electron spin-state changes in transition-metal (TM) complexes underpin many biochemical processes and molecular spin-control technologies. Such transitions, triggered by external stimuli like temperature, light, or pressure, alter both the molecular structure and electron spin density (ESD) distribution. Paramagnetic NMR offers atomic-scale insights into these changes, yet traditional solution-state measurements bear limitations due to solvent effects, unaccounted lattice cooperativity, and inaccessibility at cryogenic temperatures. We overcome these limitations by extending the approach to spinning solids at cryogenic temperatures. Specifically, we report high-resolution

Indexed as

First principle calculationsSolid‐state NMRSpin crossoverTransition metal complexes

Identifiers

PMID41369190
PMCPMC12811660

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.