A 4,4',4″-nitrilotriphenoxyl radical derived from Yang's biradical.

Qiong-Yan Hong, Bin Huang, Yanfei Niu, Cuihong Wang, Xiao-Li Zhao, Hai-Bo Yang, Xueliang Shi

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Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

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7 authors.

Qiong-Yan HongState Key Laboratory of Petroleum Molecular & Process Engineering, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University Shanghai 200062 China xlshi@chem.ecnu.edu.cn.

Bin HuangState Key Laboratory of Petroleum Molecular & Process Engineering, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University Shanghai 200062 China xlshi@chem.ecnu.edu.cn.

Yanfei NiuState Key Laboratory of Petroleum Molecular & Process Engineering, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University Shanghai 200062 China xlshi@chem.ecnu.edu.cn.

Cuihong WangState Key Laboratory of Petroleum Molecular & Process Engineering, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University Shanghai 200062 China xlshi@chem.ecnu.edu.cn.

Xiao-Li ZhaoState Key Laboratory of Petroleum Molecular & Process Engineering, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University Shanghai 200062 China xlshi@chem.ecnu.edu.cn.ORCID https://orcid.org/0000-0002-4458-6432

Hai-Bo YangState Key Laboratory of Petroleum Molecular & Process Engineering, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University Shanghai 200062 China xlshi@chem.ecnu.edu.cn.ORCID https://orcid.org/0000-0003-4926-1618

Xueliang ShiState Key Laboratory of Petroleum Molecular & Process Engineering, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University Shanghai 200062 China xlshi@chem.ecnu.edu.cn.ORCID https://orcid.org/0000-0002-6453-0751

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Phenoxyl radicals have attracted considerable attention due to their unique electronic structures and wide-ranging applications in physics, chemistry, biology, and materials science. Herein, we report the synthesis and in-depth characterization of a previously unreported 4,4',4″-nitrilotriphenoxyl radical 3, structurally derived from Yang's biradical scaffold. Interestingly, electronic structure analyses reveal that 3 is a monoradical with an open-shell doublet ground state, wherein the unpaired electron is delocalized over the three peripheral 2,6-di-

Identifiers

PMID41368493

DOI10.1039/d5sc06789h

PMCPMC12683543

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