Stabilization of the Benzene Radical Trianion in an Inverse-Sandwich Yttrium Complex.

Weiqing Mao, Saroshan Deshapriya, Shenglai Yao, Christian Lorent, Matthias Driess, Selvan Demir

Abstract read

In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed

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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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3 · Its place in the literature

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0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

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5 · Who and what money

Authors and funding

6 authors.

Weiqing MaoDepartment of Chemistry: Metalorganics and Inorganic Materials, Technische Universität Berlin, Strasse des 17. Juni 135, Sekr. C2, 10623, Berlin, Germany.

Saroshan DeshapriyaDepartment of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan, 48824, USA.ORCID https://orcid.org/0000-0002-4438-2894

Shenglai YaoDepartment of Chemistry: Metalorganics and Inorganic Materials, Technische Universität Berlin, Strasse des 17. Juni 135, Sekr. C2, 10623, Berlin, Germany.

Christian LorentDepartment of Chemistry, Physical and Biophysical Chemistry, Technische Universität Berlin, Strasse des 17. Juni 135, Sekr. PC14, 10623, Berlin, Germany.

Matthias DriessDepartment of Chemistry: Metalorganics and Inorganic Materials, Technische Universität Berlin, Strasse des 17. Juni 135, Sekr. C2, 10623, Berlin, Germany.ORCID https://orcid.org/0000-0002-9873-4103

Selvan DemirDepartment of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan, 48824, USA.ORCID https://orcid.org/0000-0001-7983-9850

Funding

German Research Foundation EXC 2008-390540038National Science Foundation CHE-2339595

6 · The paper itself

Abstract

Herein, the first report on the isolated and unambiguously proven benzene radical trianion is presented. This unprecedented radical oxidation state of benzene is stabilized through two trivalent rare earth (RE) metal cations each supported by a bis(guanidinate) scaffold. Specifically, the one-electron chemical reduction of the neutral inverse-sandwich yttrium complex [[{(Me

Indexed as

AromaticityDensity functional theory calculationsEPR spectroscopyOrganic radical anionsRare‐earth metals

Identifiers

PMID41363814

DOI10.1002/anie.202521849

PMCPMC13007589

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.