Evidence map›Paper›PMID 41358685›Full record

ArticleJournal of the American Chemical Society2025

Development, Scope, and Catalyst Selection in Boron-Catalyzed Iterative Glycosylation.

Kishor R Harale, Chandana Sunil, Girish C Sati, Annabel Q Ansel, Timothy M Emmel, Joshua L Martin, Taylor E Spiller, John Montgomery

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Conformationally constrained glycosyl fluoride donors enable chemoselective glycosylation.Organic chemistry frontiers : an international journal of organic chemistry · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Kishor R HaraleDepartment of Chemistry, University of Michigan, 930 N. University Ave., Ann Arbor, Michigan 48109-1055, United States.
Chandana SunilDepartment of Chemistry, University of Michigan, 930 N. University Ave., Ann Arbor, Michigan 48109-1055, United States.
Girish C SatiDepartment of Chemistry, University of Michigan, 930 N. University Ave., Ann Arbor, Michigan 48109-1055, United States.
Annabel Q AnselDepartment of Chemistry, University of Michigan, 930 N. University Ave., Ann Arbor, Michigan 48109-1055, United States.ORCID 0000-0002-7456-5827
Timothy M EmmelDepartment of Chemistry, University of Michigan, 930 N. University Ave., Ann Arbor, Michigan 48109-1055, United States.ORCID 0000-0001-6026-6650
Joshua L MartinDepartment of Chemistry, University of Michigan, 930 N. University Ave., Ann Arbor, Michigan 48109-1055, United States.ORCID 0000-0002-6719-9339
Taylor E SpillerDepartment of Chemistry, University of Michigan, 930 N. University Ave., Ann Arbor, Michigan 48109-1055, United States.
John MontgomeryDepartment of Chemistry, University of Michigan, 930 N. University Ave., Ann Arbor, Michigan 48109-1055, United States.ORCID 0000-0002-2229-0585

Funding

Supplement: Regio- and Site-Selective Processes Using Transition Metal and Biological CatalystsR35GM118133 · NIGMS · UNIVERSITY OF MICHIGAN AT ANN ARBOR · PI JOHN MONTGOMERY · 2016 to 2026
$4.9M
NIGMS NIH HHS R35 GM118133
6 · The paper itself

Abstract

Boron-catalyzed glycosylations provide an effective strategy for the rapid and simple preparation of glycosidic bonds by using glycosyl fluoride donors and silyl ether acceptors. This study examines the utility of this reaction type in iterative glycosylations, where the sequence of formation of glycosidic bonds with silyl ether acceptors is governed by a trialkyl silane structure rather than the inherent reactivity of the hydroxyl precursors. Relative rates and selectivities of glycosylations were studied by

Identifiers

PMID41358685
PMCPMC12695066

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.