Evidence map›Paper›PMID 41356613›Full record

ArticleNature synthesis2025

Direct access to a neutral alumene via CO reduction by a dialane and further CO homologation.

John A Kelly, Arseni Kostenko, Shigeyoshi Inoue

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature synthesis, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. CO homologation and isocyanide activation by a trisilyl alane radical anion.Chemical communications (Cambridge, England) · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

John A KellyTUM School of Natural Sciences, Department of Chemistry, Catalysis Research Center and Institute of Silicon Chemistry, Technische Universität Müchen (TUM), Garching Bei München, Germany.ORCID 0009-0006-4252-1535
Arseni KostenkoTUM School of Natural Sciences, Department of Chemistry, Catalysis Research Center and Institute of Silicon Chemistry, Technische Universität Müchen (TUM), Garching Bei München, Germany.ORCID 0000-0002-9593-4468
Shigeyoshi InoueTUM School of Natural Sciences, Department of Chemistry, Catalysis Research Center and Institute of Silicon Chemistry, Technische Universität Müchen (TUM), Garching Bei München, Germany.ORCID 0000-0001-6685-6352

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Multiple bonds between heavy elements have been shown to be not only stable but also offer divergent reactivity. Accordingly, there has been a drive in research to isolate such species. Here we report on the synthesis of a compound containing an aluminium-carbon double bond (alumene). The alumene was formed by exposing a dialane to a CO atmosphere. Experimental data and quantum chemical calculations confirm the existence of a

Indexed as

Chemical bonding

Identifiers

PMID41356613
PMCPMC12680539

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.