Identifying Reactivity Differences of Two-Carbon-Atom-Based Legacy Refrigerants at Group 9 Metal Pincer Complexes.

Luc A Mauro, Isabelle A Herlinger, Shane J Hall, Russell P Hughes, Roger E Cramer, Lisa A Fredin, David A Vicic

Abstract read

In one paragraph

Article in ACS organic & inorganic Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed

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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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3 · Its place in the literature

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0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

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5 · Who and what money

Authors and funding

7 authors.

Luc A MauroDepartment of Chemistry, Lehigh University, 6 E Packer Ave., Bethlehem, Pennsylvania 18015, United States.ORCID https://orcid.org/0009-0006-9228-8663

Isabelle A HerlingerDepartment of Chemistry, Lehigh University, 6 E Packer Ave., Bethlehem, Pennsylvania 18015, United States.ORCID https://orcid.org/0009-0007-8000-4536

Shane J HallDepartment of Chemistry, Lehigh University, 6 E Packer Ave., Bethlehem, Pennsylvania 18015, United States.

Russell P HughesDepartment of Chemistry, 6128 Burke Laboratory, Dartmouth College, Hanover, New Hampshire 03755, United States.ORCID https://orcid.org/0000-0002-1891-6530

Roger E CramerDepartment of Chemistry, University of Hawaii, 2545 McCarthy Mall, Honolulu, Hawaii 96822, United States.ORCID https://orcid.org/0000-0002-3934-3401

Lisa A FredinDepartment of Chemistry, Lehigh University, 6 E Packer Ave., Bethlehem, Pennsylvania 18015, United States.

David A VicicDepartment of Chemistry, Lehigh University, 6 E Packer Ave., Bethlehem, Pennsylvania 18015, United States.ORCID https://orcid.org/0000-0002-4990-0355

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We describe the first comparative data on metal-mediated C-H activation and functionalization reactions at two-carbon-atom legacy refrigerants and density functional theory (DFT) analyses on the resulting organometallic products. We reveal that, depending on the degree of fluorination in the refrigerant, C-H activation could lead either to stable M-(H)-R

Indexed as

C−H activationfluoroalkanesfluoroolefinshydrofluorocarbonsiridium pincer complexesrefrigerants

Identifiers

PMID41356452

DOI10.1021/acsorginorgau.5c00071

PMCPMC12679306

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.