ArticleBMC chemistry2025
Exploring ionic behavior: conductance studies of L-glutamic acid in aqueous D-sorbitol across temperature gradients.
Article in BMC chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
In this paper molecular interactions of L-glutamic acid (Glu) in aqueous D-sorbitol (D-SOR) are analyzed by measuring electrical conductivity in the broad temperature range of 293.15-313.15 K at ambient pressure. The density and viscosity data were also measured experimentally required to explore the derived conductometric properties. Meanwhile, the molar conductance ([Formula: see text], limiting molar conductance[Formula: see text], Walden product ([Formula: see text]), ion association constants ([Formula: see text]) and activation energy ([Formula: see text] of ion association are derived and discussed in the light of ion-ion and ion-solvent interactions. The Kraus-Bray model was used to analyze the limiting molar conductance ([Formula: see text]) of the solutions. For the mixtures under study, the increased [Formula: see text] values for Glu in aqueous D-SOR compared to pure water suggest a synergistic interaction. As D-SOR concentration increases, [Formula: see text] of Glu decreases due to stronger solute-cosolute interactions and reduced ion dissociation. Glu functions as a structure creator in water, according to the [Formula: see text] finding. However, in aqueous D-SOR, increasing temperature and D-SOR concentration cause [Formula: see text] to drop, indicating structure-breaking behavior. Numerous energy and environmental applications may benefit from an investigation of the conductometric properties of Glu and D-SOR in aqueous solutions.
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