ArticleACS omega2025
Kinetic and Thermodynamic Investigation into the Formation of Diol-Boric Acid Complexes Using NMR and Computational Analysis.
Article in ACS omega, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Borate-Bridged Protolipids: A Prebiotic Route to Abiotic Membranes.Life (Basel, Switzerland) · 2026Article
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Boric acid (BA) readily forms reversible covalent B-O bonds with diols, yielding complexes with broad implications for drug delivery, materials science, and polymer chemistry. While this chemistry is well-established in aqueous environments, little is known about the formation of neutral boron complexes with BA in organic solvents. Here, we describe a spectroscopic and theoretical study of the complexation of diols with BA in DMSO. NMR spectroscopy was used to evaluate the formation of complexes for three structurally distinct diols: ethylene glycol (EG), 1,3-propanediol (PD), and 1,4-butanediol (BD). Results indicate that with BA, PD forms the most closed B-O complex, while EG forms a mixture of open and closed B-O species, and BD forms only small amounts of the open diol-BA complex. These findings were supported computationally for both PD and EG, where the Δ
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