ArticleChemistry (Weinheim an der Bergstrasse, Germany)2026
Photochemistry of Aromatic N-Oxides in Water Probed by Time-Resolved X-ray Absorption Spectroscopy.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Aromatic N-oxides have a rich photochemistry, but the primary steps have not been investigated in much detail. In this work pyridine N-oxide and pyridazine N-oxide are studied using steady-state and time-resolved X-ray absorption spectroscopy (XAS). Absorption changes at the nitrogen and oxygen K-edges following UV photoexcitation are recorded on a timescale of picoseconds to hundreds of nanoseconds. The spectral features are assigned to the presence of specific transient intermediates. Quantum chemical calculations indicate that the excited state dynamics in the S
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