ArticleAngewandte Chemie (International ed. in English)2026
Harnessing Cooperative Energy Transfer and Hydrogen Atom Transfer for Direct Nitrogenations of Non-Activated Alkanes.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Who cites it
1 citing paper in PubMed.
- Harnessing Cooperative Energy Transfer and Hydrogen Atom Transfer for Direct Nitrogenations of Non-Activated Alkanes.Angewandte Chemie (International ed. in English) · 2026Article
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5 authors.
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Abstract
While important progress has been achieved recently on direct functionalization of alkanes via photocatalytic methods, direct amination of aliphatic compounds remains a great challenge. Herein we report a conceptually new strategy towards direct conversion of hydrocarbons into amines, based on in situ generation of nitrene radical. Energy transfer between thioxanthone (TXO) photocatalyst and iminoiodinane furnishes the triplet nitrene radical, able to undergo HAT reaction promoting alkane activation and subsequent C─N bond formation step. The user-friendly nature of the metal-free transformation, along with mild reaction conditions further highlight the sustainability of this scalable process delivering a diversity of cycloalkylamines. Combined experimental and computational mechanistic studies support the unusual reaction mechanism.
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