ArticlePrecision chemistry2025
Programmable Multi-State Fluorescence Switching on a Dynamic Molecular System via Sequential Dynamic Covalent Chemistry and Applications.
Article in Precision chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Dynamic molecular systems capable of controlled transformations are foundational for developing next-generation intelligent materials and sensors. However, achieving sequential, multistate switching with distinct optical outputs on a single molecular platform remains challenging. Here, we introduce a class of dynamic fluorescent systems built upon a single benzo-conjugated acceptor. This system undergoes programmed molecular reconfiguration and fluorescence switching through sequential chemical and pH-driven triggers, leveraging intramolecular oxa/thiol-Michael addition-elimination reactions via dynamic covalent bonding in aqueous medias. Each distinct molecular state exhibits unique, trackable absorbance and fluorescence signatures, governed by precisely controlled pseudo-p
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