Evidence map›Paper›PMID 41311949›Full record

ArticleJACS Au2025

Control of Conical Intersection Dynamics in CF

Dong Yan, Huimin Zhang, Fangfang Li, Mingjuan Yang, Jiaxing Liu, Yujie Ma, Ang Xu, Ti Zhou, Minghui Yang, Mingfei Zhou and 1 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in JACS Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Dong YanDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Fudan University, Shanghai 200438, P. R. China.
Huimin ZhangState Key Laboratory of Magnetic Resonance Spectroscopy and Imaging, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan 430071, P. R. China.
Fangfang LiDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Fudan University, Shanghai 200438, P. R. China.
Mingjuan YangState Key Laboratory of Magnetic Resonance Spectroscopy and Imaging, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan 430071, P. R. China.
Jiaxing LiuDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Fudan University, Shanghai 200438, P. R. China.
Yujie MaDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Fudan University, Shanghai 200438, P. R. China.
Ang XuDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Fudan University, Shanghai 200438, P. R. China.
Ti ZhouDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Fudan University, Shanghai 200438, P. R. China.
Minghui YangState Key Laboratory of Magnetic Resonance Spectroscopy and Imaging, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan 430071, P. R. China.ORCID https://orcid.org/0000-0003-1067-2217
Mingfei ZhouDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Fudan University, Shanghai 200438, P. R. China.ORCID https://orcid.org/0000-0002-1915-6203
Fengyan WangDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Fudan University, Shanghai 200438, P. R. China.ORCID https://orcid.org/0000-0003-2366-7038

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The dynamics of conical intersections are critical in governing the diverse pathways of chemical reactions, especially in photoexcited polyatomic systems. However, the systematic control of conical intersection dynamics remains a formidable challenge in reaction dynamics. Here, we demonstrate that halogen bonding, a key type of noncovalent interaction between halogenated molecules and electron-rich species, can control the conical intersection dynamics of halogenated compounds. Using time-sliced ion velocity map imaging with high resolution, we investigate the ultraviolet photodissociation dynamics of CF

Indexed as

chemical reaction controlnonadiabatic transitionnoncovalent intersectionspin−orbit couplingtime-sliced ion velocity imaging

Identifiers

PMID41311949
PMCPMC12648343

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.