Solvent-mediated chirality inversion in orthogonal hierarchical assembly of achiral carbene-anchored gold cluster.

Ying-Jie Liu, Wen-Qiu Yu, Yu Liu, Xiao-Wen Qi, Shuang-Quan Zang

Abstract read

In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

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1citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

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3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

Stacking the Deck to Make Materials With Atypically Short Heterometallic dAngewandte Chemie (International ed. in English) · 2026
Article

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5 · Who and what money

Authors and funding

5 authors.

Ying-Jie LiuHenan Key Laboratory of Crystalline Molecular Functional Materials, College of Chemistry, Zhengzhou University, Zhengzhou, 450001, China.

Wen-Qiu YuHenan Key Laboratory of Crystalline Molecular Functional Materials, College of Chemistry, Zhengzhou University, Zhengzhou, 450001, China.

Yu LiuHenan Key Laboratory of Crystalline Molecular Functional Materials, College of Chemistry, Zhengzhou University, Zhengzhou, 450001, China.

Xiao-Wen QiHenan Key Laboratory of Crystalline Molecular Functional Materials, College of Chemistry, Zhengzhou University, Zhengzhou, 450001, China.

Shuang-Quan ZangHenan Key Laboratory of Crystalline Molecular Functional Materials, College of Chemistry, Zhengzhou University, Zhengzhou, 450001, China. zangsqzg@zzu.edu.cn.ORCID http://orcid.org/0000-0002-6728-0559

Funding

China Postdoctoral Science Foundation 2021TQ0294National Natural Science Foundation of China (National Science Foundation of China) 22105177National Natural Science Foundation of China (National Science Foundation of China) 92356304National Natural Science Foundation of China (National Science Foundation of China) 92461304Natural Science Foundation of Henan Province (Henan Province Natural Science Foundation) 252300421174

6 · The paper itself

Abstract

Precisely constructing homochiral helical nanostructures from achiral molecules by non-covalent interactions remains challenging owing to the untraceable handedness control at different hierarchical levels. Here, we present an aurophilicity-assisted orthogonal assembly strategy, enabling not only the homochiral assembly of an achiral carbene-anchored trinuclear gold cluster with chiral amines but also the inversion of circularly polarized luminescence (CPL). This gold cluster could spontaneously form random right- or left-handed helices, while introduction of chiral amines effectively drives the formation of hierarchically homochiral twists with |g

Identifiers

PMID41298441

DOI10.1038/s41467-025-65637-8

PMCPMC12657935

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.