ArticleNature communications2025
A DMAP-enabled strategy for C(sp
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
3 citing papers in PubMed.
- Deoxygenative functionalization of alcohols, ethers, and carbonyl compounds by chromium catalysis.Science advances · 2026Article
- Mg-Mediated Dual Cross-Electrophile Coupling of Propargyl and Allyl Dichlorides with Chlorosilanes: Access to Disilyl-substituted Allene and Bis(Silyl)Propenes.Angewandte Chemie (International ed. in English) · 2026Article
- Nickel/Photoredox Dual-Catalyzed Migratory Reductive C(spAngewandte Chemie (International ed. in English) · 2026Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
7 authors.
Funding
Abstract
Organosilanes find extensive utility in numerous fields, and thus attract significant interest in methodological developments for their synthesis. Conventional approaches predominantly rely on nucleophilic substitutions using pre-synthesized and highly reactive organometallic reagents. While recent advances in the coupling of commercial carbon electrophiles with halosilanes circumvent the need for these sensitive nucleophiles, such systems often require meticulously optimized catalysts, and the applicability of substrate scope often differentiates case-by-case. Herein, we report a general and robust 4-(dimethylamino)pyridine-enabled platform for C(sp²)-Si bond formation between organic halides and halosilanes. Combined experimental and computational studies reveal a dual role of DMAP in activating both inert Csp
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.