ArticleGels (Basel, Switzerland)2025
Mechanically Reinforced Silica Aerogels via Thermally Induced Phase Separation of Poly(ethylene-co-vinyl Alcohol).
Article in Gels (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Silica aerogels are highly attractive due to their outstanding properties, including their low density, ultralow thermal conductivity, large porosity, high optical transparency, and strong sorption activity. However, their inherent brittleness has limited widespread applications. Constructing a robust, highly porous three-dimensional network is critical to achieving the desired mechanical properties in aerogels. In this study, we introduce a novel synthesis route for fabricating lightweight and mechanically strong aerogels by incorporating poly(ethylene-co-vinyl alcohol) (EVOH) through thermally induced phase separation (TIPS). EVOH exhibits upper critical solution temperature (UCST) behavior in a mixture of isopropanol (IPA) and water, which can be utilized to reinforce the silica skeletal structure. Robust aerogels were prepared via the sol-gel process and TIPS method, followed by supercritical CO
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