ArticleJournal of the American Chemical Society2025
Neutron Diffraction and Spectroscopic Studies of Intramolecular Tetrel Bonds in Three Fluorinated Zinc Complexes: Significant Redshift in the sp
Norman Lu, Gurumallappa Gurumallappa, Pin-Yu Liu, Ka-Long Chan, Yu-Cheng Huang, Yu-Ching Lin, Yun-Ting Hsieh, Pin-Xiang Zeng, Yashwanth Gowda, Meng-Hsun Tsai and 3 more
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In one paragraphArticle in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Not yet cited in PubMed.
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13 authors.
Norman LuInstitute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan (ROC).ORCID 0000-0002-3554-6113 Gurumallappa GurumallappaInstitute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan (ROC).ORCID 0000-0002-0806-0142 Pin-Yu LiuInstitute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan (ROC).
Ka-Long ChanInstitute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan (ROC).ORCID 0000-0003-4491-996X Yu-Cheng HuangInstitute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan (ROC).
Yu-Ching LinInstitute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan (ROC).
Yun-Ting HsiehInstitute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan (ROC).ORCID 0009-0007-9269-2188 Pin-Xiang ZengInstitute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan (ROC).
Yashwanth GowdaInstitute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan (ROC).ORCID 0009-0003-5067-3721 Meng-Hsun TsaiInstitute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan (ROC).
Eskedar TessemaInstitute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan (ROC).ORCID 0000-0002-4514-8688 Huan-Cheng ChangInstitute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan (ROC).ORCID 0000-0002-3515-4128 Joseph S FranciscoDepartment of Earth and Environmental Science and Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6316, United States.ORCID 0000-0002-5461-1486 Funding
No grant is acknowledged in the PubMed record.
6 · The paper itselfAbstract
Three fluorinated Zn complexes were synthesized and characterized. Their single crystals were grown and studied via X-ray and neutron diffraction methods. These fluorinated metal complexes tend to form two special noncovalent interactions: an intramolecular tetrel bond (TB) and an intramolecular blueshifting hydrogen bond (HB). In 4FH-ZnCl
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PMID41292364
PMCPMC12703683
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