Evidence map›Paper›PMID 41280797›Full record

ArticleACS omega2025

In-Depth Analysis of the Paramagnetic Properties in DHI/DHICA-Controlled Eumelanin.

João V Paulin, João P Cachaneski-Lopes, Emanuele Carrella, Alessandro Pezzella, Augusto Batagin-Neto, Carlos F O Graeff

Abstract read
In one paragraph

Article in ACS omega, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

João V PaulinSchool of Sciences, Department of Physics and Meteorology, São Paulo State University (UNESP), Bauru, São Paulo 17033-360, Brazil.ORCID https://orcid.org/0000-0002-2379-6203
João P Cachaneski-LopesGraduate Program in Materials Science and Technology (POSMAT), São Paulo State University (UNESP), Bauru, São Paulo 17033-360, Brazil.
Emanuele CarrellaDepartment of Chemical Sciences, University of Naples Federico II, via Cinthia 4, Naples 80126, Italy.
Alessandro PezzellaDepartment of Physics Ettore Pancini, University of Naples Federico II, Via Vicinale Cupa Cintia, 21, Naples 80126, Italy.ORCID https://orcid.org/0000-0001-6925-922X
Augusto Batagin-NetoGraduate Program in Materials Science and Technology (POSMAT), São Paulo State University (UNESP), Bauru, São Paulo 17033-360, Brazil.ORCID https://orcid.org/0000-0003-4609-9002
Carlos F O GraeffSchool of Sciences, Department of Physics and Meteorology, São Paulo State University (UNESP), Bauru, São Paulo 17033-360, Brazil.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Eumelanin, a naturally occurring pigment derived from the oxidative polymerization of 5,6-dihydroxyindole (DHI) and 5,6-dihydroxyindole-2-carboxylic acid (DHICA), has been extensively studied for its role in human biology and its potential applications in biomedical and sustainable electronic fields. By employing X-band electron paramagnetic resonance spectroscopy, this study focuses on eumelanin with different DHI/DHICA ratios, directly comparing monomeric and polymeric forms. The analysis reveals significant differences in the paramagnetic profiles, with changes in spin dynamics and relaxation times closely linked to the distinct macrostructures formed during polymerization. These findings offer valuable insights into how the molecular architecture of eumelanin influences its paramagnetic environments.

Identifiers

PMID41280797
PMCPMC12631427

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.