Evidence map›Paper›PMID 41277063›Full record

ArticleAngewandte Chemie (International ed. in English)2026

Homoleptic Bismuth Alkynes: Isolable Reagents for Selective Alkynyl Radical Transfer.

Gargi Kundu, Felix Debbeler, Sascha Reith, Frerik Wurm, Alicia Casitas, Crispin Lichtenberg

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Gargi KunduFachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Str. 4, 35032, Marburg, Germany.
Felix DebbelerFachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Str. 4, 35032, Marburg, Germany.
Sascha ReithFachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Str. 4, 35032, Marburg, Germany.
Frerik WurmFachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Str. 4, 35032, Marburg, Germany.
Alicia CasitasFachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Str. 4, 35032, Marburg, Germany.
Crispin LichtenbergFachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Str. 4, 35032, Marburg, Germany.ORCID https://orcid.org/0000-0002-0176-0939

Funding

Deutsche Forschungsgemeinschaft LI2860/5-1H2020 European Research Council 946184LOEWE program
6 · The paper itself

Abstract

Alkynyl radicals represent highly attractive building blocks in synthetic chemistry but keep posing considerable challenges to researchers in the field. While their existence in interstellar space, in combustion processes, and under matrix-isolation conditions has been documented, access under typical wet-chemical conditions remains limited. In this context, bismuth compounds are promising candidates as their ability to engage in controlled radical reactions has recently been brought into the focus of research efforts. Here, we present the first synthesis and full characterization of a series of homoleptic bismuth alkyne compounds, Bi(C≡CR)

Indexed as

Alkynyl radicalBismuth alkynesC–C couplingRadical borylationThermal activation

Identifiers

PMID41277063
PMCPMC12828473

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.