ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Skeletal Editing of Alkenes with Nitroarenes via Photoinduced Rearrangement of N─O═C Dipoles Forms Lactams and Amides.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Photoinduced H-Bonding EDA complex-enabled skeletal editing of furans to pyridazines.Nature communications · 2026Article
- Skeletal Editing of Alkenes with Nitroarenes via Photoinduced Rearrangement of N─O═C Dipoles Forms Lactams and Amides.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
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8 authors.
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Abstract
Photoinduced oxidative cleavage of alkenes with nitroarenes has proven to be an efficient approach for generating N─O = C dipoles. These dipoles exhibit diverse reactivity profiles, making the rearrangement of N─O═C dipoles a promising strategy for achieving nitrogen atom insertion in skeletal editing. Herein, we present a novel protocol for the synthesis of diverse lactam and amide derivatives through skeletal editing of alkenes using nitroarenes as nitrogen atom insertion reagents under light irradiation, offering the advantages of operational simplicity, high efficiency, and sustainability. Mechanistic studies and DFT calculations indicate that it proceeds through an intramolecular synergistic cyclization-cleavage-rearrangement process involving N─O═C dipoles, which realizes the cascade cleavage of C(sp
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