ArticleMikrochimica acta2025
Tunable dual-ligand ZIF-8-90 effervescent tablet-assisted dispersive solid phase extraction for monitoring of both PAHs and their hydroxyl metabolites: from external to internal exposure analysis.
Article in Mikrochimica acta, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Mixed-ligand metal organic frameworks have received great attentions as novel sorbents for sample preparation due to their fascinating structures and intriguing functionalities. Here, we report the fabrication of mixed-linker ZIF-8-90 s with tunable properties for effervescent tablet-assisted dispersive solid-phase extraction (ET-DSPE) of polycyclic aromatic hydrocarbons (PAHs) in environmental water before HPLC separation and hydroxyl metabolites of PAHs (OH-PAHs) in urine samples prior to LC-MS/MS. ZIF-8-90 s based effervescent tablets possessed the high affinity towards analytes via Zn-O bond and π-π interaction, and afforded a great excluding ability to interfering components from urine samples. ET-DSPE of PAHs from 15 mL water sample with ZIF-8
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