Evidence map›Paper›PMID 41266395›Full record

ArticleNature communications2025

Diaryl Bismuthides and Acyl Bismuthanes Enable Visible-Light-Induced Reversible Carbon Monoxide Insertion and Extrusion.

Felix Geist, Benedikt Narz, Darian Boguslawski, Tobias Dunaj, Sascha Reith, Jordi Poater, Crispin Lichtenberg

Abstract read
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Felix GeistDepartment of Chemistry Philipps-Universität Marburg, Hans-Meerwein-Str. 4, Marburg, Germany.ORCID http://orcid.org/0009-0006-8032-7581
Benedikt NarzDepartment of Chemistry Philipps-Universität Marburg, Hans-Meerwein-Str. 4, Marburg, Germany.
Darian BoguslawskiDepartment of Chemistry Philipps-Universität Marburg, Hans-Meerwein-Str. 4, Marburg, Germany.
Tobias DunajDepartment of Chemistry Philipps-Universität Marburg, Hans-Meerwein-Str. 4, Marburg, Germany.ORCID http://orcid.org/0000-0001-5459-8480
Sascha ReithDepartment of Chemistry Philipps-Universität Marburg, Hans-Meerwein-Str. 4, Marburg, Germany.ORCID http://orcid.org/0000-0002-2747-0809
Jordi PoaterDepartament de Química Inorgànica i Orgànica & IQTCUB, Universitat de Barcelona, Barcelona, Spain.ORCID http://orcid.org/0000-0002-0814-5074
Crispin LichtenbergDepartment of Chemistry Philipps-Universität Marburg, Hans-Meerwein-Str. 4, Marburg, Germany. crispin.lichtenberg@chemie.uni-marburg.de.ORCID http://orcid.org/0000-0002-0176-0939

Funding

Deutsche Forschungsgemeinschaft (German Research Foundation) LI2860/5-1EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council) 946184
6 · The paper itself

Abstract

Carbon monoxide (CO) is one of the simplest and most fundamental molecules that has fascinated chemists for decades. Early-on, chemists have recognized and exploited its favorable properties as a key reagent in large-scale metallurgical processes, productions of base- and fine chemicals, and (more recently) potential medical applications. Most of these transformations rely on reactions that proceed in the coordination sphere of transition metals, with reversible reactions playing a crucial role in catalytic transformations. Recent endeavors have brought main group elements on the stage of carbonyl chemistry (carbonyl = metal-bound CO), but reversible reactions (especially insertion and extrusion reactions) are very rare and remain limited to examples of thermal initiation. Here we show that an innovative access to acyl-bismuth compounds, R

Identifiers

PMID41266395
PMCPMC12635283

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.